SAFETY DATA SHEET
2,4-DICHLOROBENZYL PEROXIDE PASTE
1. IDENTIFICATION
Product Identifiers
Product Name:
2,4-DICHLOROBENZYL PEROXIDE PASTE
Other Names:
BEN PEROX PASTE
Product Number(s):
C037
CAS Number:
-
Recommended use of the chemical and restriction on use
Laboratory use.
Company Details
ProSciTech Pty Ltd
11 Carlton Street
KIRWAN QLD 4817
Australia(07) 4773 9444www.proscitech.com
11 Carlton Street
KIRWAN QLD 4817
Australia(07) 4773 9444www.proscitech.com
Emergency Contact Details
ProSciTech Pty Ltd
11 Carlton Street
KIRWAN QLD 4817
Australia(07) 4773 9444www.proscitech.com
11 Carlton Street
KIRWAN QLD 4817
Australia(07) 4773 9444www.proscitech.com
2. HAZARDS IDENTIFICATION
Classification of the substance or mixture
GHS02 flame.
H242 Heating may cause a fire.
GHS06 skull and crossbones.
H301 Toxic if swallowed.
GHS08 health hazard.
H360 May damage fertility or the unborn child.
GHS07
H332 Harmful if inhaled.
H319 Causes serious eye irritation.
H317 May cause an allergic skin reaction.
H242 Heating may cause a fire.
GHS06 skull and crossbones.
H301 Toxic if swallowed.
GHS08 health hazard.
H360 May damage fertility or the unborn child.
GHS07
H332 Harmful if inhaled.
H319 Causes serious eye irritation.
H317 May cause an allergic skin reaction.
Label Elements
Signal Words
Danger
Hazard Statement(s)
Toxic if swallowed.
Harmful if inhaled.
Causes serious eye irritation.
May cause an allergic skin reaction.
May damage fertility or the unborn child
Harmful if inhaled.
Causes serious eye irritation.
May cause an allergic skin reaction.
May damage fertility or the unborn child
Precautionary Statement(s)
Obtain special instructions before use.
Do not handle until all safety precautions have been read and understood.
Keep away from heat/sparks/open flames/hot surfaces.
No smoking.
Keep/Store away from clothing/combustible materials.
Keep only in original container.
Avoid breathing dust/fume/gas/mist/vapours/spray.
Wash thoroughly after handling.
Do not eat, drink or smoke when using this product.
Use only outdoors or in a well-ventilated area.
Contaminated work clothing should not be allowed out of the workplace.
Wear protective gloves / eye protection / face protection.
Do not handle until all safety precautions have been read and understood.
Keep away from heat/sparks/open flames/hot surfaces.
No smoking.
Keep/Store away from clothing/combustible materials.
Keep only in original container.
Avoid breathing dust/fume/gas/mist/vapours/spray.
Wash thoroughly after handling.
Do not eat, drink or smoke when using this product.
Use only outdoors or in a well-ventilated area.
Contaminated work clothing should not be allowed out of the workplace.
Wear protective gloves / eye protection / face protection.
Primary route(s) of entry
IF exposed or concerned: Get medical advice/attention.
Call a POISON CENTER/doctor if you feel unwell.
Specific treatment (see on this label).
Rinse mouth.
If skin irritation or rash occurs: Get medical advice/attention.
If eye irritation persists: Get medical advice/attention.
Wash contaminated clothing before reuse.
Call a POISON CENTER/doctor if you feel unwell.
Specific treatment (see on this label).
Rinse mouth.
If skin irritation or rash occurs: Get medical advice/attention.
If eye irritation persists: Get medical advice/attention.
Wash contaminated clothing before reuse.
Human Health
Inhalation:
Remove victim to fresh air and keep at rest in a position comfortable for breathing.
Ingestion:
Immediately call a POISON CENTER/ doctor.
Eyes:
Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
Skin:
Wash with plenty of water.
Environment
Dispose of contents/container in accordance with local/regional/national/international regulations.
3. COMPOSITION/INFORMATION ON INGREDIENTS
Name
CAS No.
Content (w/w)
Classification
dibenzoyl peroxide
94-36-0
50-100
-
dibutyl phthalate
84-74-2
2.5-10%
-
-
-
-
-
4. FIRST AID MEASURES
Ingestion
Do not induce vomiting; call for medical help immediately.
Inhalation
Supply fresh air and to be sure call for a doctor.
In case of unconsciousness place patient stably in side position for transportation.
In case of unconsciousness place patient stably in side position for transportation.
Skin Contact
Immediately wash with water and soap and rinse thoroughly.
Eye Contact
Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor.
Other Information
Immediately remove any clothing soiled by the product. In case of irregular breathing or respiratory arrest provide artificial respiration.
5. FIREFIGHTING MEASURES
Suitable extinguishing equipment
CO₂, powder or water spray. Fight larger fires with water spray or alcohol resistant foam.
HAZCHEM
Not available.
Special protective equipment and precautions for fire fighters
6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
Not required.
Environmental precautions
No special measures required.
Methods and materials for containment and clean up
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Dispose contaminated material as waste according to item 13. Ensure adequate ventilation.
Dispose contaminated material as waste according to item 13. Ensure adequate ventilation.
7. HANDLING AND STORAGE
Precautions for safe handling
Ensure good ventilation/exhaustion at the workplace. Open and handle receptacle with care. Prevent formation of aerosols.
Conditions for safe storage
Store locked up.
Protect from sunlight.
Store away from other materials.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Exposure Standards
Engineering controls
Protect from heat.
Keep respiratory protective device available.
Keep respiratory protective device available.
Personal protective equipment
Eye and face protection
Tightly sealed goggles.
Skin protection
Protective gloves
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the chemical mixture.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation ·
Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the application.
Penetration time of glove material
The exact break through time has to be found out by the manufacturer of the protective gloves and has to be observed.
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the chemical mixture.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation ·
Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the application.
Penetration time of glove material
The exact break through time has to be found out by the manufacturer of the protective gloves and has to be observed.
Body protection
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing
Wash hands before breaks and at the end of work.
Store protective clothing separately.
Avoid contact with the eyes.
Avoid contact with the eyes and skin.
Immediately remove all soiled and contaminated clothing
Wash hands before breaks and at the end of work.
Store protective clothing separately.
Avoid contact with the eyes.
Avoid contact with the eyes and skin.
Respiratory protection
In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use self-contained respiratory protective device.
9. PHYSICAL AND CHEMICAL PROPERTIES
General information
Appearance
White pasty
Odour
Mild
pH
Not determined.
Vapour Pressure
at 20 °C: 23 hPa
Density
1.2025 g/cm³
Boiling Point
100 °C
Melting Point
Undetermined.
Solubility
Not miscible or difficult to mix with water.
Specific Gravity of Density
Not determined.
Flash Point
Not applicable.
Flammable (Explosive) Limits
Lower: 0.1 Vol %
Upper: 2.0 Vol %
Upper: 2.0 Vol %
Ignition Temperature
390 °C
Formula
Not available.
10. STABILITY AND REACTIVITY
Reactivity
No further relevant information available.
Chemical stability
No decomposition if used according to specifications
Possibility of hazardous reactions
No dangerous reactions known.
Conditions to avoid
No further relevant information available.
Incompatible materials
No further relevant information available.
11. TOXICOLOGICAL INFORMATION
Acute effects
LD/LC50 values relevant for classification:
84-74-2 dibutyl phthalate
Oral LD50 8000 mg/kg (rat)
Dermal LD50 20000 mg/kg (rabbit)
84-74-2 dibutyl phthalate
Oral LD50 8000 mg/kg (rat)
Dermal LD50 20000 mg/kg (rabbit)
Eye contact
Irritating effect.
Skin contact
No irritant effect.
Ingestion
No further relevant information available.
Inhalation
Sensitisation possible through skin contact.
Toxicity and irritation
No further relevant information available.
12. ECOLOGICAL INFORMATION
Ecotoxicity
No further relevant information available.
Persistence and degradability
No further relevant information available.
Bioaccumulative potential
No further relevant information available.
Other adverse effects
Not known to be hazardous to water.
13. DISPOSAL CONSIDERATIONS
General information
Must not be disposed together with household garbage. Do not allow product to reach sewage system.·
Uncleaned packaging: ·
Recommendation: Disposal must be made according to official regulations.
Uncleaned packaging: ·
Recommendation: Disposal must be made according to official regulations.
14. TRANSPORT INFORMATION
ADG label required
HAZCHEM
Not available.
UN Number
UN3106
Proper shipping name
3106 ORGANIC PEROXIDE TYPE D, SOLID
Transport hazard class
Void
Packing group
II
Environmental hazard
No
Yes (DOT)
Yes (DOT)
Special precautions for users
Warning: Organic peroxides.
Additional information
Limited quantities (LQ) 500 g
Excepted quantities (EQ) Code: E0 Not permitted as Excepted Quantity.
Excepted quantities (EQ) Code: E0 Not permitted as Excepted Quantity.
15. REGULATORY INFORMATION
Poisons Schedule Number
S2, S4, S5
Other Information
No further relevant information available.
16. OTHER INFORMATION
SDS preparation date
18 September 2017
Comments
This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship.
This Safety Data Sheet (SDS) has been prepared in compliance with the Preparation of Safety Data Sheets for Hazardous Chemicals Code of Practice February 2016. It is the user's responsibility to determine the suitability of this information for adoption of necessary safety precautions. The information published in this SDS has been compiled from the publications listed in Section 16: to the best of our ability and knowledge these publications are considered accurate. We reserve the right to revise Safety Data Sheets as new information becomes available. Copies may be made for non-profit use.